Null-transmission ellipsometry and depolarized light microscopy have been performed on free-standing films of three achiral banana-shaped compounds in the B2 phase. Our results support a two-layer unit cell previously proposed to explain the observed antiferroelectricity in thin films and bulk samples. We have studied thicker films than previously reported and have found no deviations in the film structure from the earlier findings. Moreover, we can determine the layer spacing, the molecular tilt from the layer normal, and the three principal indices of refraction in the molecular reference frame.
Physical Review E
Copyright 2001 American Physical Society. Available on publisher's site at http://dx.doi.org/10.1103/PhysRevE.63.041702
Olson, D. A.; Veum, M.; Cady, A.; D'Agostino, M. V.; Johnson, P. M.; Nguyen, H. T.; Chien, Liang-Chy; Huang, C. C. (2001). Optical Studies of the Liquid Crystal B2 Phase Formed by Banana-Shaped Molecules. Physical Review E 63(4) doi: 10.1103/PhysRevE.63.041702. Retrieved from https://oaks.kent.edu/cpippubs/151