The simple nematic mesogen 5CB was doped with milled BaTiO3 nanoparticles and was investigated with x-ray scattering. Doping with BaTiO3 nanoparticles of 9 nm in diameter led to the formation of crystallites. These crystallites precipitated and formed a waxlike nanodispersion of 5CB and nanoparticles, which led to intense x-ray scattering signals characteristic of a multilayer structure. Surprisingly, the multilayers possess unusual interlayer spacing, which cannot be explained by simple smectic order of the calamitic molecules.
Physical Review E
Copyright 2012 American Physical Society. Available on publisher's site at http://dx.doi.org/10.1103/PhysRevE.86.051704.
Lorenz, Alexander; Zimmerman, Natalie; Kumar, Satyendra; Evans, Dean R.; Cook, Gary; Kitzerow, Hienz-S. (2012). Doping the Nematic Liquid Crystal 5Cb With Milled Batio3 Nanoparticles. Physical Review E 86(5) doi: 10.1103/PhysRevE.86.051704. Retrieved from https://oaks.kent.edu/phypubs/27